Pascal Gerbaux
Pascal Gerbaux
  • +32 (0)65 37 33 42

Organic Synthesis and Mass Spectrometry Lab
University of Mons – Umons



Visting Scientist at the University of Utrecht with Prof Heck


Visiting Scientist at the University of Washington with Prof Turecek


Senior Research Associate of the “Fonds National de la Recherche Scientifique


Research associate of the ‘Fonds National de la Recherche Scientifique’


Postdoctoral Researcher of the ‘Fonds National de la Recherche Scientifique’


Research Fellow of the ‘Fonds National de la Recherche Scientifique’


Ph.D. in Chemistry at UMons


M.Sc. in chemistry at UMons



Pascal Gerbaux is Professor of Organic Chemistry and Mass Spectrometry at the University of Mons in Belgium. He is also the head of the Organic Synthesis and Mass Spectrometry Laboratory that is today constituted by around 15 people. He is also in charge of the Mass Spectrometry Center at the UMons that is equipped with eight mass spectrometers, including the unique Waters AutoSpec 6F and a brand new Waters Synapt G2-Si mass spectrometer. He has developed a strong expertise in the field of organic mass spectrometry and is acknowledged for his involvement in the so-called Gas Phase Ion Chemistry studies. His domain of research nowadays concerns the development of mass spectrometry methods for the structural characterization of supramolecular assemblies, macromolecules and natural products.


Research Interest

Mass spectrometry


Professional Activities:

Research field and academic responsabilities

A. Research:

  1. Fundamental studies of the physicochemical phenomena related to modern methods of mass spectrometry
  2. Study of the chemistry of ionized species in the gas phase
  3. Application of mass spectrometry to organic, macromolecular and supramolecular chemistry
  4. Many scientific partnerships using the analytical aspect of mass spectrometry: chemistry of organometallic compounds, identification of natural products ...

B. Responsibilities related to research:

  1. Head (scientific, administrative, educational and financial) of the Mass Spectrometry facilities in UMons
  2. Founding member of the Interdisciplinary Center for Mass Spectrometry of UMons (CISMa)
  3. Manager of a strong technologic platform of 8 complementary mass spectrometers. Supervision of Master (20 from 2005) and PhD (8 from 2007) theses in the field of mass spectrometry
  4. Financial support awarded in 2015 (500.000 euros) for the acquisition of a new ion mobility mass spectrometer
  5. Responsible for the interuniversity service activity for organic and macromolecular chemistry (> 800 samples / year)
  6. Member of the Belgian Society for Mass Spectrometry committee (BSMS).
  7. Organization of the annual conference of the BSMS in 2011
  8. Supervision of many trainees from Europe, America, Asia and Africa.



Publications: 156 articles are published or accepted for publication in journals with peer-reviewing process: 44 publications as the first or last author.
Lectures and oral presentations: 37 oral presentations were given in national or international conferences
Poster Presentations: 75 posters were presented in national or international conferences
Active participation in 25 international conferences abroad

  1. “Elucidation of Molecular Diversity and Body Distribution of Saponins in the Sea Cucumber Holothuria forskali (Echinodermata) by Mass Spectrometry.” Séverine Van Dijck, Pascal Gerbaux et Patrick Flammang, Comparative Biochemistry & Physiology, Part.B : Biochemistry and Molecular Biology. 152 (2009) 124-134.
  2. “Oligonucleotide duplexes with tethered photoreactive Ru(II) complexes: influence of the ligands and their linker on the photoinduced electron transfer and crosslinking processes of the two strands.” Stéphanie Deroo, Stéphane Le Gac, Sumana Gosh, Mathilde Villien, Pascal Gerbaux, Eric Defrancq, Cécile Moucheron, Pascal Dumy, Andrée Kirsch – De Mesmaeker, Eur.J.Inorg.Chem. (2009) 524-532.
  3. “Photoreactive Ru(II) complex tethered to a guanine-containing oligonucleotide : a biomolecular tool that behaves as a Seppuku molecule.” Stéphane Le Gac, S. Rickling, Pascal Gerbaux, Eric Defrancq, Cécile Moucheron, Andrée Kirsch – De Mesmaeker, Ang .Chem.Int. Ed.Engl., 48 (2009) 1122-1125.
  4. “Metastable processes investigated on an oa-ToF instrument: mass-scale calibration and application.” Julien De Winter, Anne-Lise Goffin, Olivier Coulembier, Philippe Dubois, Robert Flammang et Pascal Gerbaux, Eur.J.Mass Spectrom., 15 (2009) 431- 437.
  5. “Microsomal glutathione transferase 1 exhibits one-third-of-the-sites-reactivity towards glutathione.” Johan Alander, Johan Lengqvist, Peter J Holm, Richard Svensson, Pascal Gerbaux, Robert H H van den Heuvel, Hans Herbert, William J Griffiths, Richard N Armstrong, Ralf Morgenstern, Archives of Biochemistry and Biophysics, 487 (2009) 42- 48. (FI 2.578).
  6. ”Conversion of natural aldehydes from Eucalyptus Citriodora, Cymbopogon Citratus and Lippia Multiflora to oximes : GC-MS and FT-IR Analysis.” Igor W.Ouédraogo, Michaël Boulvin, Robert Flammang, Pascal Gerbaux, Yvonne L.Bonzy-Coulibaly. Molecules, 14 (2009) 3275- 3285.
  7. “The quest for the elusive carbodiimide ion HN=C=NH•+ and its generation from ionized cyanamide by proton-transport catalysis.”  Karl J. Jobst, Pascal Gerbaux, Gina Dimopolous-Italiano, Paul J.A. Ruttink, Johan K. Terlouw, Chem.Phys.Lett., 478 (2009) 144-149.
  8. “Differentiation of the pyridine radical cation from its distonic isomers by ion-molecule reactions with dioxygen.” Karl Jobst, Julien De Winter, Robert Flammang, Johan K Terlouw and Pascal Gerbaux. Int.J.Mass Spectrom., 286 (2009) 83-88.
  9. ”Reactions of Ionized Methyl Benzoate with Methyl Isocyanide in the Gas-Phase: Nucleophilic Aromatic Substitutions vs Hydrogen Migrations.” Guy Bouchoux, Julien De Winter, Robert Flammang, Pascal Gerbaux, J.Phys.Chem.A, 113 (2009) 11075-11083.
  10. ”The reaction of the acrylonitrile ion CH2=CH-CºN·+ with HCN : Proton-transport catalysis vs formation of ionized pyrimidine.” Henri K.Ervasti, Karl J.Jobst, Pascal Gerbaux, Peter C. Burgers, Paul J.A. Ruttink, Johan K. Terlouw, Chem.Phys.Lett., 482 (2009) 211-216.
  11. ”Incorporation of different end-groups in conjugated polymers using functional nickel initiators.” Alfons Smeets, Julien De Winter, Pascal Gerbaux, Thierry Verbiest, and Guy Koeckelberghs, Macromolecules, 42 (2009) 7638-7641.
  12. “From jellyfish macromolecular architectures to nano-doughnut self-assembly.” Olivier Coulembier, Sébastien Moins, Julien De Winter, Pascal Gerbaux, Philippe Leclère, Roberto Lazzaroni et Philippe Dubois. Macromolecules, 43 (2010) 575-579.
  13. “Metastable dimethyl phthalate molecular ions: does the loss of a methoxyl radical proceed with or without anchimeric assistance?” Pascal Gerbaux, Robert Flammang, Julien De Winter, Vinh Son Nguyen, Minh Tho Nguyen. Int.J.Mass Spectrom., 290 (2010) 127-132.
  14. “Qualitative and quantitative study of Saponin contents of five sea cucumbers of the Indian Ocean.” Séverine Van Dyck, Pascal Gerbaux et Patrick Flammang. Marine Drugs, 8 (2010) 173-189.
  15. “Cobalt-mediated radical coupling (CMRC): an unusual route to symmetrical macromolecules.” Antoine Debuine, Rinaldo Poli, Julien Dewinter, Pascal Laurent, Philippe Dubois, Pascal Gerbaux, Jean-Paul Wathelet, Christine Jérôme et Christophe Detrembleur. Chem.Eur.J., 6 (2010) 1799-1811.
  16. “Synthesis and supramolecular organization of regioregular polythiophene block oligomers.” Sébastien Clément, Franck Meyer, Julien De Winter, Olivier Coulembier, Christophe ML Vende Velde, Matthias Zeller, Pascal Gerbaux, Jean-Yves Balandier, Sergey Sergeyev, Roberto Lazzaroni, Yvers Geerts et Philippe Dubois. J.Org.Chem., 75 (2010) 1561-1568.
  17. “Effective Cobalt-Mediated Radical Coupling (CMRC) of Poly(vinyl acetate) and Poly(N-vinylpyrrolidone) (Co)polymers Precursors.” Antoine Debuigne, Rinaldo Poli, Julien De Winter, Pascal Laurent, Pascal Gerbaux, Jean-Paul Wathelet, Christine Jérôme, Christophe Detrembleur, Macromolecules, 43 (2010) 2801-2813.
  18. “Regioregular poly(3-hexylthiophene—poly(e-caprolactone) block copolymers: controlled synthesis, microscopic morphology and charge transport properties.” Mathieu Surin, Olivier Coulembier, Khoa Tran, Julien De Winter, Philippe Leclère, Pascal Gerbaux, Roberto Lazzaroni, Philippe Dubois, Organic Electronics, 11 (2010) 767-774.
  19. “A rigid dinuclear Ru(II) complex as efficient photo-activable reagent for bridging two guanine bases of a duplex or quadruplex oligonucleotide.” S.Rickling, L.Ghisdavu, F.Piérard, P.Gerbaux, M.Surin, P.Murat, E.Defrancq, C.Moucheron and A.Kirsch-De Mesmaeker, Chem.Eur.J., 16 (2010) 3951-3961.
  20. “Mechanistic study on the collision-induced dissociation of sodium-cationized polylactide oligomers : a joint experimental and theoretical investigation.” Julien De Winter, Vincent Lemaur, Olivier Coulembier, Jérôme Cornil, Philippe Dubois, Pascal Gerbaux. J.Am.Soc. Mass Spectrom., 21 (2010) 1159-1168.
  21. “Aromatic substitution reactions between ionized benzene derivatives and neutral methyl isocyanide.” Guy Bouchoux, Julien De Winter, Robert Flammang et Pascal Gerbaux. J.Phys.Chem.A, 114 (2010) 7408-7416.
  22. “Imidazolium versus Polycyclic Aromatics containing poly(L-lactide) for Carbon Nanotube Dispersion in Organic Media.” Franck Meyer, Jean-Marie Raquez, Olivier Coulembier, Julien De Winter, Pascal Gerbaux, Philippe Dubois. Chem.Commun., 46 (2010) 5527-5529.
  23. “A Ru(II) TAP complex, photoreagent for Tryptophan containing peptides: Structure of the covalent photo-adduct.” Nicolas Gauthier, Julien De Winter, Pascal Gerbaux, Cécile Moucheron, Michel Luhmer and Andrée Kirsch - De Mesmaeker, Inorganic Chemistry, 49 (2010) 6796-6798.
  24. “Comparison of Matrix assisted Laser Desorption / Ionization Mass Spectrometry with Electrospray Ionisation Mass Spectrometry for the characterisation of semi-telechelic polyethylene oxide.” Julien De Winter, Magali Vachaudez, Olivier Coulembier, Philippe Dubois, Robert Flammang, Pascal Gerbaux. e-polymers, (2010) e103 (10 pages).
  25. “Photoreactive Ru(II)-oligonucleotide conjugates: influence of an intercalating ligand on the inter- and intra-strand photo-ligation processes.” Stéphane Le Gac, Martin Foucart, Pascal Gerbaux, Eric Defrancq, Cécile Moucheron, et Andrée Kirsch-De Mesmaeker, Dalton Transactions, 39 (2010) 9672-9683.
  26. “High molecular weight poly(a,a’,b-trisubstituted b-lactones) as generated by metal-free phosphazene catalysts.” Julien De Winter, Olivier Coulembier, Pascal Gerbaux et Philippe Dubois. Macromolecules, 43 (2010) 10291-10296.
  27.  “Novel regioregular poly(3-hexylthiophene)-based polycationic block copolymers.” Ha Tran Nguyen, Olivier Coulembier, Pascal Gerbaux, Julien De Winter, Xavier Crispin, and Philippe Dubois. Polymer Bulletin, 66 (2011) 51-64.
  28.  “Review of saponin diversity in sea cucumbers belonging to the family Holothuriidae.” Guillaume Caulier, Séverine Van Dyck, Pascal Gerbaux, Igor Eeckhaut, Patrick Flammang. SPC Beche-de-mer, Bulletin #31, (2011) 48-54.
  29.  “Towards the Understanding of Plasma Polymer Film Behavior in Ethanol: A Multi-Technique Investigation.” Laurent Denis, Damien Thiry, Damien Cossement, Pascal Gerbaux, Fabiola Brusciotti, Isabel Van De Keere, Veerle Goossens, Herman Terryn, Michel Hecq, Rony Snyders. Progress in Organic Coatings, 70 (2011) 134-141.
  30.  “Synthesis and characterization of p-conjugated polymer / silica hybrids containing regioregular ionic polythiophenes”. Sébastien Clément, Akim Tizit, Simon Desbief,Ahmad Mehdi, Julien De Winter, Pascal Gerbaux, Roberto Lazzaroni and Bruno Boury. Journal of Materials Chemistry, 21 (2011) 2733-2739.
  31.  “The Ni-catalyzed Polymerization of Poly(3-alkoxythiophene)s.” Karlien Van den Bergh, Julien De Winter, Pascal Gerbaux, Thierry Verbiest, and Guy Koeckelberghs, Macromolecular Chemistry and Physics, 212 (2011) 328-335.
  32.  “MALDI-ToF analysis of polythiophene : use of trans-2-[3-(4-t-Butyl-phenyl)-2-methyl-2-propenylidene]malononitrile – DCTB – as matrix.” Julien De Winter, Gaëlle Deshayes, Florian Boon, Olivier Coulembier, Philippe Dubois, Pascal Gerbaux. Journal of Mass Spectrometry, 46 (2011) 237-246.
  33.  “The triterpene glycosides of Holothuria forskali: usefulness and efficiency as a chemical defense mechanism against predatory fish.” Séverine Van Dyck, Guillaume Caulier, Pascal Gerbaux, Isabelle Fournier, Maïté Todesco, Maxence Wisztorski, Patrick Flammang. Journal of Experimental Biology, 214 (2011) 1347-1356.
  34.  “A simplified protocol for bumble bee species identification by cephalic secretion analysis.” Thibaut De Meulemeester, Pascal Gerbaux, Michaël Boulvin, Audrey Coppée, Pierre Rasmont. Insectes Sociaux, 58 (2011) 227-236.
  35.  “Size dependence of the folding of multiply charged sodium cationized polylactides revealed by ion mobility mass spectrometry and molecular modelling.” Julien De Winter, Vincent Lemaur, Renaud Ballivian, Fabien Chirot, Olivier Coulembier, Rodolphe Antoine, Jérôme Lemoine, Jérôme Cornil, Philippe Dubois, Philippe Dugourd, Pascal Gerbaux. Chem.Eur.J., 17 (2011) 9738-9745.
  36.  “End Group-functionalization and Synthesis of Block-copolythiophenes by Modified Nickel Initiators.” Alfons Smeets, Pieter Willot, Julien De Winter, Pascal Gerbaux, Thierry Verbiest and Guy Koeckelberghs, Macromolecules, 44 (2011) 6017-6025.
  37.  “Collision-induced dissociation of polymer ions : charge driven decomposition for sodium-cationized polylactides.” Julien De Winter, Olivier Coulembier, Philippe Dubois, Pascal Gerbaux, In.J.Mass Spectrom., 308 (2011) 11-17.
  38.  “Rotaxane-based mechanically linked Block Copolymer.” Guillaume De Bo, Julien De Winter, Pascal Gerbaux, Charles-André Fustin, Ang.Chem., Int.Ed.Engl., 50 (2011) 9093-9096 .
  39.  “Collision-induced dissociation of flavonoid 7-O-diglycoside cations: elucidation of important structural motifs by selection of the cationizing reaction.” Ousmane Ilboudo, Issa Tapsoba, Yvonne L. Bonzi-Coulibaly et Pascal Gerbaux. Eur.J.Mass Spectrom., 17 (2011) 557-572.
  40.  “Photocrosslinking between Peptide-Peptide or Peptide-Oligonucleotide by RuII-TAP Complexes using a DNA duplex as template. Covalent photoaddition of two tryptophan moieties on the Ru complex.” Jonathan Ghesquière, Nicolas Gauthier, Julien De Winter, Pascal Gerbaux, Cécile Moucheron, Eric Defrancq et Andrée Kirsch - De Mesmaeker, Chem.Eur.J, 18 (2012) 355-364.
  41.  “Gas Phase Ion Chemistry and Organic Chemistry: the story of a hybrid six sector mass spectrometer - the “AutoSpec 6F.” Pascal Gerbaux, Luc Lamote, Yves Van Haverbeke, Robert Flammang and Jeffery Brown, Eur.J.Mass Spectrom., 18 (2012) 93-112.
  42.  “Traces Do Matter - Purity of 4-Methyl-2-Oxetanone and Consequence in Anionic Ring-Opening Polymerization Evidenced by Phosphazene Superbases Catalysis.” Michał Kawalec, Olivier Coulembier, Pascal Gerbaux, Michał Sobota, Julien De Winter, Philippe Dubois, Marek Kowalczuk and Piotr Kurcok, Reactive and Functional Polymers, 72 (2012) 509-520.
  43. "A Supramolecular Approach Toward Straightforward Fabrication of Graphene-Polymer Nanocomposites." Sunil Lonkar, Alexis Bobenrieth, Julien De Winter, Pascal Gerbaux, Jean-Marie Raquez and Philippe Dubois, Chemistry of Materials, 22 (2012) 18124-18126.
  44.  “Synthesis and characterization of carboxystyryl end-functionalized poly(3-hexylthiophene)/TiO2 hybrids in view of photovoltaic applications.”  Florian Boon, Guylhaine Clavel, Julien De Winter, Danielle Laurencin, Amandine Thomas, Olivier Coulembier, Philippe Dubois, Pascal Gerbaux, Roberto Lazzaroni, Sébastien Richeter, Ahmad Mehdi and Sébastien Clément, Synthetic Metals, 162 (2012) 1615-1622.
  45.  “Thermally-induced coupling of poly(thiophene) based block copolymers prepared by Grignard metathesis polymerization: a straightforward route towards highly regioregular multiblock conjugated copolymers.” Farid Ouhib,  Simon Desbief, Roberto Lazzaroni, Julien De Winter, Pascal Gerbaux, Christine Jerôme and Christophe Detrembleur, Macromolecules, 45 (2012) 6796-6806.
  46.  “Imidazole-based organocatalyst designed for bulk polymerization of lactide isomers: inspiration from Nature.” Olivier Coulembier, Thomas Josse, Brieuc Guillerm, Pascal Gerbaux, and Philippe Dubois, Chem.Commun., 48 (2012) 11695-11697.
  47.  “Qualitative and quantitative analysis of flavonoid diglycosides in leaves of Mentha piperita L by MALDI-MS/MS and LC-MS.” Ousmane Ilboudo, Igor W. Ouédraogo, Issa Tapsoba, Pascal Gerbaux et Yvonne L. Bonzi-Coulibaly, Natural Products, An indian Journal, 8 (2012) 321-327.
  48.  “Using MALDI mass spectrometry to determine the structure and composition of different molecules of ruthenium complex-peptides.” Long Le Quoc, Pascal Gerbaux, Anh Nguyen Hoang and Ha Vu Thi Thu, Vietnam Journal of Chemistry, 50 (2012) 188-194.
  49.  “Targeting structural motifs of flavonoid diglycosides using collision-induced dissociation experiments on flavonoid/Pb2+ complexes.” Ousmane Ilboudo, Issa Tapsoba, Yvonne L. Bonzi-Coulibaly and Pascal Gerbaux, Eur.J.Mass Spectrom., 18 (2012) 465-473.
  50.  “Mass Spectrometry of Cyclopentadienylideneketene. Differentiation of Isomeric Ion Structures by Means of Ion-Molecule Reactions.” Pascal Gerbaux and Curt Wentrup, Aus.J.Chem., 65 (2012) 1655-1661.
  51.  “Macrocyclic regioregular poly(3-hexylthiophene): from controlled synthesis to nanotubular assemblies” Olivier Coulembier, Gaelle Deshayes, Mathieu Surin, Julien De Winter, Florian Boon, Cécile Delcourt, Philippe Leclère, Roberto Lazzaroni, Pascal Gerbaux and Philippe Dubois, Polymer Chemistry, 4 (2013) 237-241.
  52.  “Analytical aspects of marinobufagenin.” Charline Lenaerts, Marie Demeyer, Pascal Gerbaux and Bertrand Blankert, Clinica Chimica Acta, 421 (2013), 193-201.
  53.  “Synthesis of Poly[(4,4’-(dihexyl)dithieno(3,2-b;2’,3’-d)silole] and Copolymerization with 3-Hexylthiophene: New Semiconducting Materials with Extended Optical Absorption." Florian Boon, Noémie Hergué, Gaëlle Deshayes, David Moerman, Julien De Winter, Pascal Gerbaux, Yves H. Geerts, Roberto Lazzaroni, Philippe Dubois, Polymer Chemistry, 4 (2013), 4303 – 4307.
  54.  “Homotropic allosterism: in-depth structural analysis by mass spectrometry and computational chemistry of the gas-phase non covalent complexes associating a double-cavity cucurbit[n]uril-type host and size-selected protonated amino compounds.”   Vincent Lemaur, Glenn Carroy, Frédéric Poussigue, Fabien Chirot, Julien De Winter, Lyle Isaacs, Philippe Dugourd, Jérôme Cornil, Pascal Gerbaux, ChemPlusChem, 78 (2013) 959 – 969.
  55.  “When repellent holothuroid saponins become attractive kairomones.” Guillaume Caulier, Patrick Flammang, Pascal Gerbaux and Igor Eeckhaut. Scientific Reports 3, (2013) article number: 2639. 
  56.  “Peculiar properties of homoleptic Cu complexes with dipyrromethene derivatives.” Kathleen Servaty, Emilie Cauët, Fabrice Thomas, Javiera Lambermont, Pascal Gerbaux, Julien De Winter, Margriet Ovaere, Leen Volker, Nathalie Vaeck, Luc Van Meervelt, Wim Dehaen, Cécile Moucheron and Andrée Kirsch- De Mesmaeker, Dalton Trans., 42 (2013) 14188 – 14199.
  57.  “Volatility profiles of monoterpenes loaded onto cellulosic‒ based materials” Igor W. K. Ouédraogo, Julien De Winter, Pascal Gerbaux, Yvonne L. Bonzi-Coulibaly, Industrial Crops and Products, 51 (2013) 100 – 106.
  58.  “Preservation of the bioactive saponins of Holothuria scabra through the processing of trepan.” Guillaume Caulier, Patrick Flammang, Priscillia Rakotorisoa, Pascal Gerbaux and Igor Eeckhaut. Proceedings of the International Conference on Echinoderms, Cah. Biol. Mar., 54 (2013) 685-690.
  59.  “An unprecedented method for oxidizing quinoxaline, tetraazaphenanthrene and hexaazatriphenylene moieties using hypervalent iodine [bis(trifluoroacetoxy)iodo]benzene and (diacetoxy)iodobenzene.” Ludovic Troian-Gautier, Julien De Winter, Pascal Gerbaux, Cécile Moucheron. J.Org.Chem., 78 (2013) 11096−11101.
  60.  “The reaction between the hydrogen-bridged radical cation [NH2C=O--H--O=CH2]•+ and dioxygen.” Karl J. Jobst, Johan K. Terlouw, Julien De Winter and Pascal Gerbaux, Int.J.Mass Spectrom., 354–355 (2013) 99–104.
  61.  “Study of the controlled chain-growth polymerization of poly(3,6-dioctyl oxy phenantrene).” Michiel Verswyvel, Charly Hoebers, Julien De Winter, Pascal Gerbaux  and Guy Koeckelberghs, Journal of Polymer Science Part A: Polymer Chemistry, 51 (2013) 5067-5074.
  62.  “Molecular Diversity and Body Distribution of Saponins in the Sea Star Asterias rubens by Mass Spectrometry.” Marie Demeyer, Julien De Winter, Guillaume Caulier, Igor Eeckhaut, Patrick Flammang, Pascal Gerbaux, Comparative Biochemistry & Physiology, Part.B : Biochemistry and Molecular Biology, 168 (2014) 1-11.
  63.  “Nitroxide mediated polymerization of methacrylates at moderate temperature.” Christophe Detrembleur, Julien De Winter, Pascal Gerbaux, Jean-Louis Clément, Yohann Guillaneuf and Didier Gignes, Polymer Chemistry, 5 (2014) 335-340.
  64.  “Control over Molar mass, Dispersity, End-groups and Kinetics in Cyclopolymerization of ortho-Phthalaldehyde : Adapted Choice of Phosphazene Organocatalyst." Julien De Winter,  Andrew P. Dove, Armin Knoll, Pascal Gerbaux, Philippe Dubois and Olivier Coulembier, Polymer Chemistry, 5 (2014) 706-711.
  65.  “Ambient Temperature Catalyst-Free Light-Induced Preparation of Macrocyclic Aliphatic Polyesters.” Thomas Josse, Ozcan Altintas, Kim K. Oehlenschlaeger, Philippe Dubois, Pascal Gerbaux, Olivier Coulembier and Christopher Barner-Kowollik, Chem.Commun., 50 (2014) 2024- 2026.
  66.  “One-step synthesis of polylactide macrocycles from sparteine-initiated ROP” Olivier Coulembier, Julien De Winter, Laetitia Mespouille, Pascal Gerbaux, Philippe Dubois, Polymer Chemistry, 5 (2014) 2103- 2108.
  67.  “Study on the formation of a supramolecular conjugated graft-copolymer in solution.” Tine Hardeman, Pieter Willot, Julien De Winter, Pascal Gerbaux, Pavletta Shestakova, Erik Nies and Guy Koeckelberghs. J.Polym.Sc., Part A, 52 (2014) 804- 809.
  68.  Synthesis of end-group functionalized P3HT: general protocol for P3HT/nanoparticle hybrids.” Frederic Monnaie, Alfons Smeets, Julien De Winter, Pascal Gerbaux, Ward Brullot, Thierry Verbiest, and Guy Koeckelberghs, Macromolecules, 46 (2013) 8500–8508.
  69. All-conjugated cationic copolythiophene “rod-rod” block copolyelectrolytes: synthesis, optical properties and solvent dependent assembly.” Amandine Thomas, Judith E. Houston, Niko Van den Brande, Julien De Winter, Michèle Chevrier, Richard K. Heenan, Sébastien Richeter, Ahmad Mehdi, Bruno Van Mele, Philippe Dubois, Roberto Lazzaroni, Pascal Gerbaux, Rachel C. Evans and Sébastien Clément, Polymer Chemistry, 5 (2014) 3352-3362.
  70. “Combining mass spectrometry diagnostic and DFT calculations for a better understanding of the plasma polymerization of ethyl lactate.”  S. Ligot, M. Guillaume, P. Gerbaux, D. Thiry, F. Renaux, J. Cornil, P. Dubois, R. Snyders, J.Phys.Chem.C, 118 (2014) 4201-4211.
  71.  “The Elusive Ethenediselone, Se=C=C=Se.“ Carl. Th. Pedersen, Ming Wah Wong, Kazuo Takimiya, Pascal Gerbaux, and Robert Flammang, Aus.J.Chem., 67 (2014) 1195-1200.
  72.  “Poly(ethylene imine) impurities induce n-doping reaction in organic (semi)conductors” Simone Fabiano, Slawomir Braun, Xianjie Liu, Pascal Gerbaux, Mats Fahlman, Magnus Berggren and Xavier Crispin, Advanced Materials,  26 (2014) 6000–6006.
  73.  “Design of multi-stimuli responsive shape-memory polymer materials by reactive extrusion” Florence Pilate, Rosica Mincheva, Julien De Winter, Pascal Gerbaux, Linbo Wu, Richard Todd, Jean-Marie Raquez, and Philippe Dubois, Chemistry of Materials, 26 (2014) 5860–5867.
  74.  “’ Meisenheimer Complex Inspired Catalyst- and Solvent-Free Synthesis of Non-Cyclic Poly(aryl ether sulfone)s" Jeannette Garcia, Gavin Jones, Julien De Winter, Hans Horn, Olivier Coulembier, Philippe Dubois, Pascal Gerbaux, James Hedrick, Macromolecules, 47 (2014) 8131–8136.
  75.  “A tandem mass spectrometry-based method to assess the architectural purity of synthetic polymers: case of a cyclic polylactide obtained by click chemistry” Thomas Josse, Julien De Winter, Philippe Dubois, Olivier Coulembier, Pascal Gerbaux, and Antony Memboeuf, Polymer Chemistry, 6 (2015) 64–69.
  76.  “Synthesis and Transfer of Chirality in Hydrogen Bonded Supramolecular All Conjugated Diblock Copolymers” Frederic Monnaie, Ward Ceunen, Julien De Winter, Pascal Gerbaux, Valentina Cocchi, Elisabetta Salatelli, and Guy Koeckelberghs, Macromolecules, 48 (2015) 90-98.
  77.  “Photoaddition of Two Guanine Bases to Single Ru-TAP Complexes. Computational Studies and Ultrafast Spectroscopies to Elucidate the pH Dependence of Primary Processes”, Lionel Marcélis, Mateusz Rebarz, Vincent Lemaur, Eduard Fron, Julien De Winter, Cécile Moucheron, Pascal Gerbaux, David Beljonne, Michel Sliwa and Andrée Kirsch-De Mesmaeker, J.Phys.Chem.B, 119 (2015) 4488-4500.
  78.  “Sunlight-induced click reaction: an efficient route to cyclic polymers” Thomas Josse, Julien De Winter, Ozcan Altintas, Philippe Dubois, Christopher Barner-Kowollik, Pascal Gerbaux and Olivier Coulembier, Macromolecular Chemistry and Physics, 216 (2015) 1227-1234.
  79.  “ATRP-based Polymers with Modular Ligation Points under Thermal and Thermomechanical Stress”, Ozcan Altintas, Thomas Josse, Mahdi Abbasi, Julien De Winter, Vanessa Trouillet, Pascal Gerbaux, Manfred Wilhelm and Christopher Barner-Kowollik, Polymer Chemistry, 6 (2015) 2854-2868.
  80.  “Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers” Jeremy Demarteau, Anthony Kermagoret, Ian German, Daniela Cordella, Koen Robeyns, Julien De Winter, Pascal Gerbaux, Christine Jérôme, Antoine Debuigne, and Christophe Detrembleur, Chem. Commun., 51 (2015) 14334-14337.
  81.  “Effects of Holothuroid Ichtyotoxic Saponins on the Gills of Free-Living Fishes and Symbiotic Pearlfishes” Igor Eeckhaut, Guillaume Caulier, Lola Brasseur, Patrick Flammang, Pascal Gerbaux, and Eric Parmentier, Biol. Bull. 228 (2015) 253–265.
  82.  “Inter- and intra-organ spatial distributions of sea star saponins by MALDI-imaging.” Marie Demeyer, Elise Hennebert, Maxence Wisztorski, Julien De Winter, Guillaume Caulier, Igor Eeckhaut, Isabelle Fournier, Patrick Flammang, and Pascal Gerbaux, Analytical and Bioanalytical Chemistry, 407 (2015) 8813–8824.
  83.  “Ready access to end-functional polystyrenes via a combination of ARGET ATRP and thiol–ene chemistry” Ozcan Altintas, Thomas Josse, Julien De Winter, Nicholas M. Matsumoto, Pascal Gerbaux, Manfred Wilhelm and Christopher Barner-Kowollik, Polym. Chem., 6 (2015) 6931-6935.
  84.  “Parameters influencing the photo-induced electron transfer from tryptophan containing peptides to a RuII complex: a systematic study”, Kevin Garnir, Sandra Estalayo, Rémy Lartia, Julien De Winter, Eric Defrancq, Mathieu Surin, Vincent Lemaur, Pascal Gerbaux and Cécile Moucheron, Faraday Discussions, (2015) accepted.
  85.  “Occurrence of Theaspirane and its Odorant Degradation Products in Hop and Beer.” Caroline Scholtes, Sabrina Nizet, Hadrien Massart, Pascal Gerbaux, and Sonia Collin, J. Agric. Food Chem. 63 (2015) 8247-8253.
  86.  “Energy transfer in poly(3-hexylthiophene)-g-polyfluorene graft copolymers." Joost Steverlynck, Amaury De Cattelle, Julien De Winter, Pascal Gerbaux, and Guy Koeckelberghs, J.Polym.Sc., Part A: Polym.Chem., accepted.
  87.  “Influence of Structure of End-group functionalized Poly(3-hexylthiophene) and Poly(3-octylselenophene) Anchored on Au Nanoparticles.” Frederic Monnaie, Lize Verheyen, Julien De Winter, Pascal Gerbaux, Ward Brullot, Thierry Verbiest, Guy Koeckelberghs, Macromolecules, accepted.


Autoimmune Journal Flyer