Michael V. Mirkin
Michael V. Mirkin
Professor of Chemistry & Biochemistry
Queens College-CUNY
Flushing, New York, USA 
Phone: (718) 997-4111
E-mail: mmirkin@qc.cuny.edu

Education

B.S./M.S.Chemistry 1982 Kazakh State University, Alma-Ata, USSR
Ph. D. Chemistry 1987 Kazakh State University, Alma-Ata, USSR
Postdoctoral  Chemistry 1990/93 University of Texas at Austin (A.J. Bard’s group)

 

Biography

 

Research Interest

Our research interests are in the emerging field of nanoelectrochemistry.  We employ nanometer-sized electrochemical probes for molecular level characterization of chemical processes and materials.  A wide variety of phenomena are studied, including charge-transfer reactions at the solid/liquid and liquid/liquid interfaces, nucleation/growth of metals, bioelectrochemistry, and electrocatalysis.  The main focus is on obtaining quantitative physicochemical information by combination of experiments with mathematical modeling and computer simulations.We employ scanning electrochemical microscopy (SECM) to investigate the dynamics of electron and ion transfers at the interfaces and inside immobilized biological cells and to probe catalytic reactions at individual nanoparticles, and for high-resolution reactivity imaging.  We also maintain an active interest in development of electrochemical techniques for analytical applications.  These include carbon nanoprobes, pipette-based amperometric sensors, and resistive-pulse sensors.

 

Professional Activities:

Appointments:

2004-present Professor of Chemistry/Queens College – CUNY
2013 Invited Visiting Professor, Ecole Normale Supérieure, Paris, France.
1998-2004 Associate Professor of Chemistry/ Queens College – CUNY
1993-1998 Assistant Prof. of Chemistry/Queens College – CUNY

 

Publications

Books:

“Scanning Electrochemical Microscopy” (A. J. Bard and M. V. Mirkin, Eds.), Marcel Dekker, N.Y., 2001; 2nd edition CRC Press, Boca Raton, FL, 2012.

“Nanoelectrochemistry” (M. V. Mirkin and S. Amemiya, Eds.),CRC Press, Boca Raton, FL, 2015.

Articles in peer-reviewed journals and chapters in books:

  1. R. Chen, K. Hu, Y. Yu, M V. Mirkin, and S. Amemiya
    “Focused-Ion-Beam-Milled Carbon Nanoelectrodes for Scanning Electrochemical Microscopy”, J. Electrochem. Soc.2016, 163,H3032-H3037.
  2. M. Zhou, Y. Yu, P.-Y. Blanchard, and M. V. Mirkin
    “Surface Patterning Using Diazonium Ink Filled Nanopipette”, Anal. Chem.2015, 87,10956-10962.
  3. Y. Yu, T. Sun,and M. V. Mirkin
    "Scanning Electrochemical Microscopy (SECM) of Single Spherical Nanoparticles: Theory and Particle Size Evaluation", Anal. Chem.2015, 87, 7446−7453.
  4. M. Zhou, Y. Yu, K. Hu and M. V. Mirkin
    “Nanoelectrochemical Approach to Detecting Short-Lived Intermediates of Electrocatalytic Oxygen Reduction”, J. Am. Chem. Soc.2015, 137, 6517−6523.
  5. H. Cai, Y. Wang, Y. Yu, M. V. Mirkin, S. Bhakta, G. W. Bishop, A. Joshi, and J. F. Rusling
    “Resistive-Pulse Measurements with Nanopipettes: Detection of Vascular Endothelial Growth Factor C (VEGF-C) using Antibody-decorated Nanoparticles”, Anal. Chem.2015, 87, 6403–6410.
  6. T. Sun, P.-Y. Blanchard, and M. V. Mirkin “Cleaning Nanoelectrodes with Air Plasma”, Anal. Chem. 2015, 87, 4092-4095.
  7. M. V. Mirkin “Nanoelectrodes and liquid/liquid nanointerfaces”, in M. V. Mirkin and S. Amemiya (Eds.), Nanoelectrochemistry, CRC Press, Boca Raton, FL, 2015, pp. 539-572.
  8. Y. Wang, H. Cai, and M. V. Mirkin “Delivery of Single Nanoparticles from Nanopipettes under Resistive-Pulse Control”, ChemElectroChem2015, 2, 343-347.
  9. Y. Yu, Y. Gao, K. Hu, P.-Y. Blanchard,J.-M. Noël, T. Nareshkumar, K. L. Phani,G. Friedman, Y. Gogotsiand M. V. Mirkin“Electrochemistry and Electrocatalysis at Single GoldNanoparticles Attached to Carbon Nanoelectrodes”, ChemElectroChem2015, 2, 58–63.
  10. T. Sun, Y. Yu, B. J. Zacher and M. V. Mirkin “Scanning Electrochemical Microscopy of Individual Catalytic Nanoparticles”, Angew. Chem.Int. Ed.2014, 53, 14120 –14123.  (VIP article). 
  11. K. Hu, Y. Wang, H. Cai, M. V. Mirkin, Y. Gao, G. Friedman and Y. Gogotsi“Open Carbon Nanopipettes as Resistive-Pulse Sensors, Rectification Sensors and Electrochemical Nanoprobes”, Anal. Chem.2014, 86, 8897.
  12. Y. Yu, J.-M. Noël, M. V. Mirkin, Y. Gao, O. Mashtalir, G. Friedman and Y. Gogotsi“Carbon Pipette-Based Electrochemical Nanosampler”, Anal. Chem.2014,86, 3365.
  13. J. Velmurugan, J.-M. Noël and M. V. Mirkin“Nucleation and Growth of Mercury on Pt Nanoelectrodes at Different Overpotentials”, Chem. Sci.2014,5, 189.
  14. H. Watanabe, J. Velmurugan, M. V. Mirkin, M. A. Svirsky and R. R. Llinas“Scanning electrochemical microscopy as a novel proximity sensor for Atraumatic Cochlear Implant insertion”, IEEE Trans. Biomed. Eng.2014, 61, 1822.
  15. S. Amemiya, Y. Wang and M. V. Mirkin“Nanoelectrochemistry at the liquid/liquid interfaces”, in R. Compton and J. Wadhawan (Eds), Specialist Periodical Reports in Electrochemistry, Vol. 12, RSC Publishing, 2013, pp. 1–43.
  16. Y. Wang,K. Kececi, J. Velmurugan and M. V. Mirkin “Electron Transfer/Ion Transfer Mode of Scanning Electrochemical Microscopy (SECM): a New Tool for Imaging and Kinetic Studies”, Chem. Sci.2013, 4, 3606.
  17. K. Hu, Y. Gao, Y. Wang, Y. Yu, X. Zhao, S. A. Rotenberg, E. Gökmeşe, M.V. Mirkin, G. Friedman, and Y. Gogotsi“Platinized Carbon Nanoelectrodes as Potentiometric and Amperometric SECM Probes”, J. Solid State Electrochem. 2013,17, 2971.(invited article; special issue)
  18. J.-M. Noël, Y. Yu and M. V. Mirkin “Dissolution of Pt at Moderately Negative Potentials during Oxygen Reduction in Water and Organic Media”, Langmuir2013, 29, 1346.
  19. Y. Wang, K. Kececi, M. V. Mirkin,V. Mani, N. Sardesai and J. F. Rusling“Quantitative Resistive-Pulse Measurements with Nanopipettes: Detection of Au Nanoparticles and Nanoparticle-Bound Anti-peanut IgY”, Chem. Sci.2013, 4, 655.
  20. J.-M. Noël, J. Velmurugan, E. Gökmeşe and M. V. Mirkin“Fabrication, characterization and chemical etching of Ag nanoelectrodes”, J. Solid State Electrochem.2013, 17, 385 (invited article; special issue)
  21. J. Velmurugan, J.-M. Noël, W. Nogala and M.V. Mirkin “Nucleation and Growth of Metal on Nanoelectrodes”, Chem. Sci.2012, 3, 3307.
  22. L. Huang, Y. Wang, M. V. Mirkin, B. Ren and D. Zhan“Electrochemical Synthesis of Silver-tetracyanoquinodimethane Microcrystals at Agar Supported Water/1,2-Dichloroethane Interface”, J. Electrochem.2012,18, 405.(invited article; special issue)
  23. Y. Wang, J.-M. Noël, J. Velmurugan, W. Nogala, M. V. Mirkin, C. Lu, M. Guille Collignon, F. Lemaître and C. Amatore“Nanoelectrodes for Determination of Reactive Oxygen and Nitrogen Species inside Murine Macrophages”,  Proc. Natl. Acad. Sci. USA2012,109,11534.(invited article; special issue)
  24. W. Nogala, J. Velmuruganand M. V. Mirkin“Atomic Force Microscopy of Electrochemical Nanoelectrodes”, Anal. Chem.2012,84, 5192.
  25. M. V. Mirkin and Y. Wang"Theory", in A. J. Bard and M. V. Mirkin (Eds.), Scanning Electrochemical Microscopy, 2nd Ed., CRC Press, Boca Raton, FL, 2012, pp. 75-125.
  26. M. V. Mirkin and M. Tsionsky "Charge-Transfer Processes at the Liquid/Liquid Interface",in A. J. Bard and M. V. Mirkin (Eds.), Scanning Electrochemical Microscopy, 2nd Ed., CRC Press, Boca Raton, FL, 2012, pp. 191-232.
  27. M. V. Mirkin, W. Nogala, J. Velmurugan and Y. Wang“Scanning electrochemical microscopy in the 21st century. Update 1: five years after”, Phys. Chem. Chem. Phys.2011,13, 21196.
  28. P. Elsamadisi, Y. Wang, J. Velmurugan and M. V. Mirkin“Polished Nanopipets: New Probes for High-Resolution Scanning Electrochemical Microscopy”, Anal. Chem.2011, 83, 671.
  29. Y. Wang, T. Kakiuchi, Y. Yasui, and M. V. Mirkin“Kinetics of Ion Transfer at the Ionic Liquid/Water Nanointerface”, J. Am. Chem. Soc.2010, 132, 16945.
  30. Y. Wang, J. Velmurugan, M. V. Mirkin“Kinetics of Charge-Transfer Reactions at Nanoscopic Electrochemical Interfaces”, Isr. J. Chem. 2010, 50,291. (invited article; special issue)
  31. J. Velmuruganand M. V. Mirkin "Fabrication of Nanoelectrodes and Metal Clusters by Electrodeposition", ChemPhysChem2010, 11, 3011.(invited article; special issue)
  32. J. Velmurugan, D. Zhan, and M. V. Mirkin “Electrochemistry through Glass”, Nature Chem.2010, 2, 498.
  33. P. J. Rodgers, S. Amemiya, Y. Wang and M. V. Mirkin“Nanopipet Voltammetry of Common Ion across a Liquid–Liquid Interface. Theory and Limitations in Kinetic Analysis of Nanoelectrode Voltammograms”, Anal. Chem.2010, 82, 84.
  34. Y. Wang, J. Velmurugan, M. V. Mirkin, P. J. Rodgers, J. Kim and S. Amemiya“Kinetic Study of Rapid Transfer of Tetraethylammonium at the 1,2-Dichloroethane/Water Interface by Nanopipet Voltammetry of Common Ion”, Anal. Chem.2010, 82, 77.
  35. D. Zhan, J. Velmurugan and M. V. Mirkin“Adsorption/Desorption of Hydrogen on Pt Nanoelectrodes: Evidence of Surface Diffusion and Spillover”, J. Am. Chem. Soc. 2009, 131, 14756.
  36. F. O. Laforge, J. Velmurugan, Y. Wang and M. V. Mirkin“Nanoscale Imaging of Surface Topography and Reactivity with the Scanning Electrochemical Microscope (SECM)”, Anal. Chem.2009, 81, 3143.
  37. J. Velmurugan, P. Sun and M. V. Mirkin“Scanning Electrochemical Microscopy with Gold Nanotips: the Effect of Electrode Material on Electron Transfer Rates”, J. Phys. Chem. C2009, 113, 459.
  38. P. Sun, Z. Liu, H. Yu and M. V. Mirkin“Effect of Mechanical Stress on Kinetics of Heterogeneous Electron Transfer”, Langmuir2008, 24, 9941.
  39. P. Sunand M. V. Mirkin”Electrochemistry of Individual Molecules in Zeptoliter Volumes”,J. Am. Chem. Soc.2008,130, 8241.
  40. S. Amemiya, A. J. Bard, F.-R. F. Fan, M. V. Mirkin and P. R. Unwin”Scanning Electrochemical Microscopy”, Annu. Rev. Anal. Chem.2008, 1, 95.
  41. P. Sun, F. O. Laforge, T. P. Abeyweera, S. A. Rotenberg, J. Carpino and M. V. Mirkin”Nanoelectrochemistry of Mammalian Cells”, Proc. Natl. Acad. Sci. USA2008,105, 443.
  42. F. O. Laforge, P. Sunand M. V. Mirkin”Physicochemical Applications of Scanning Electrochemical Microscopy”, in S. A. Rice (Ed),Advances in Chemical Physics, Vol. 139, Wiley & Sons, 2008, pp. 177-244.
  43. P. Sun, F. O. Laforge and M. V. Mirkin”Role of Trace Amounts of Water in Transfers of Hydrophilic and Hydrophobic Ions to Low Polarity Organic Solvents”, J. Am. Chem. Soc.2007,129, 12410.
  44. F. O. Laforge, J. Carpino, S. A. Rotenbergand M. V. Mirkin”Electrochemical Attosyringe”, Proc. Natl. Acad. Sci.USA2007, 104, 11895.
  45. P. Sunand M. V. Mirkin”Scanning Electrochemical Microscopy with Slightly Recessed Nanotips”, Anal. Chem.2007, 79, 5809.
  46. L. H. Lie, M. V. Mirkin, S. Hakkarainen, A. Houlton and B. R. Horrocks"Lateral charge transport in metal complex-DNA films synthesize on Si(111) surfaces", J. Electroanal. Chem.2007, 603, 67.
  47. P. Sun, F. O. Laforge and M. V. Mirkin”Scanning Electrochemical Microscopy in the 21st Century”,Phys. Chem. Chem. Phys.2007, 9, 802.
  48. F. O. Laforge, P. Sunand M. V. Mirkin”Shuttling Mechanism of Ion Transfer Reactions at the Liquid/Liquid Interface”, J. Am. Chem. Soc.2006,128, 15019.
  49. F. O. Laforge, T. Kakiuchi, F. Shigematsu and M. V. Mirkin"Solute Partitioning and Electron Transfer at the Ionic Liquid/Water Interface",Langmuir2006, 22, 10705.
  50. P. Sun and M. V. Mirkin”Kinetics of Electron Transfer Reactions at Nanoelectrodes”, Anal. Chem.2006, 78, 6526.
  51. M. V. Mirkin“Determination of Electrode Kinetics” in Handbook of Electrochemistry, C. G. Zoski (Ed.), Elsevier,2006, pp. 639-660.
  52. F. O. Laforge and M. V. Mirkin”Scanning Electrochemical Microscopy beyond Imaging”, in Scanning Probe Microscopies Beyond Imaging, P. Samori (Ed.), Wiley-VCH,Weinheim, 2006, pp. 433-468.
  53. N. Glandut, A. D. Malec, M. V. Mirkin and M. Majda “Electrochemical Studies of the Lateral Diffusion of TEMPO in the Aqueous Liquid/Vapor Interfacial Region”, J. Phys. Chem. B2006, 110, 6101.
  54. C. Cai and M. V. Mirkin”Electron Transfer Kinetics at Polarized Nanoscopic Liquid/Liquid Interfaces”, J. Am. Chem. Soc.2006, 128, 171.
  55. H. S. Barcena, B. Liu, M. V. Mirkin and J. W. Canary"Electro-Chiroptical Molecular Switch: Mechanistic and Kinetic Studies", Inorg. Chem.2005, 44, 7652.
  56. P. Sun, F. O. Laforge and M. V. Mirkin”Ion Transfer at Nanointerfaces between Water and Neat Organic Solvents”, J. Am. Chem. Soc.2005, 127, 8596.
  57. S. A Rotenberg and M. V. Mirkin "Scanning electrochemical microscopy: Detection of human breast cancer cells by redox environment", J. Mammary Gland Biol. and Neoplasia2004, 9, 375.
  58. F. O. Laforge, T. Kakiuchi, F. Shigematsu and M. V. Mirkin"Comparative Study of Electron Transfer Reactions at the Ionic Liquid/Water and Organic/Water Interfaces", J. Am. Chem. Soc.2004, 126, 15380.
  59. C. Cai, Y. Tong and M. V. Mirkin"Probing Rapid Ion Transfer Across Nanoscopic Liquid-Liquid Interface", J. Phys. Chem. B2004,108, 17872.
  60. D. G. Georganopoulou, M. V. Mirkin and R. W. Murray"Electron transfer between Au Nanoparticles and Aqueous Redox Species at the Liquid/Liquid Interface", Nano Lett. 2004, 4, 1763.
  61. B. Liu, A. J. Bard, M. V. Mirkin and S. E. Creager"Electron Transfer at Self-Assembled Monolayers Measured by Scanning Electrochemical Microscopy",J. Am. Chem. Soc.2004, 126, 1485.
  62. W. Feng, S. A Rotenberg and M. V. Mirkin"Scanning Electrochemical Microscopy of Living Cells.5.  Imaging of Fields of Normal and Metastatic Human Breast Cells", Anal. Chem.2003, 75, 4148.
  63. M. V. Mirkin and B. R. Horrocks "Fundamentals of Scanning Electrochemical Microscopy", in J. W. Schultze, T. Osaka and M. Datta (Eds.), New Trends in Electrochemical Technology, Vol. 2, Taylor & Francis, N.Y., 2003, pp. 66-103.
  64. B. Liu, S. A Rotenberg and M. V. Mirkin "Scanning Electrochemical Microscopy of Living Cells.  4. Mechanistic Study of Charge Transfer Reactions in Human Breast Cells", Anal. Chem.2002, 74, 6340.
  65. B. Liu, M. V. Mirkin "Electron Transfer at Liquid/Liquid Interfaces.  The Effects of Ionic Adsorption, Electrolyte Concentration and Spacer Length on the Reaction Rate", J. Phys. Chem. B2002, 106, 3933.
  66. C. G. Zoski and M. V. Mirkin "Steady-State Limiting Currents at Finite Conical Microelectrodes", Anal. Chem.2002, 74, 1986.
  67. C. Cai, B. Liu, M. V. Mirkin, H. A. Frank and J. F. Rusling "Scanning Electrochemical Microscopy of Living Cells.  3.Rhodobacter Sphaeroides", Anal. Chem.2002, 74, 114.
  68. M. V. Mirkin, B. Liu and S. A Rotenberg "Probing Redox Activity of Human Breast Cells by Scanning Electrochemical Microscopy", Meth. Enzymol.2002, 352, 112.
  69. B. Liu and M. V. Mirkin "Charge Transfer Reactions at the Liquid/Liquid Interface", Anal. Chem.2001, 73, 670A.
  70. B. Liu, W. Cheng, S. A Rotenberg and M. V. Mirkin "Scanning electrochemical microscopy of living cells. 2. Imaging redox and acid-base reactivities.", J. Electroanal. Chem.2001, 500, 590.
  71. B. Liu and M. V. Mirkin "Voltammetry at Micro-ITIES", in Liquid Interfaces in Chemical, Biological, and Pharmaceutical Applications, A. G. Volkov (Ed.), Marcel Dekker, N.Y., 2001, pp. 373-398.
  72. M. V. Mirkin "Theory", in A. J. Bard and M. V. Mirkin (Eds.), Scanning Electrochemical Microscopy, Marcel Dekker, N.Y., 2001, pp. 145-200.
  73. M. V. Mirkin and M. Tsionsky "Processes at the Liquid/Liquid Interface", in A. J. Bard and M. V. Mirkin (Eds.), Scanning Electrochemical Microscopy, Marcel Dekker, N.Y., 2001, pp. 299-342.
  74. B. Liu, S. A Rotenberg and M. V. Mirkin "Scanning Electrochemical Microscopy of Living Cells: Different Redox Reactivities of Human Breast Cells and Metastatic Breast Cancer Cells", Proc. Natl. Acad. Sci.2000, 97, 9855.
  75. B. Liu, Y. Shao and M. V. Mirkin "Dual-Pipet Techniques for Probing Ionic Reactions", Anal. Chem.2000,72, 510.
  76. B. Liu and M. V. Mirkin"Electrochemistry at Microscopic Liquid-Liquid Interfaces", Electroanalysis2000, 12, 1433.
  77. M. V. Mirkin and B. R. Horrocks "Electroanalytical Measurements using the Scanning Electrochemical Microscope", Anal. Chim. Acta2000, 406, 119.
  78. B. Liu and M. V. Mirkin"Potential-Independent Electron Transfer Rate at the Liquid/Liquid Interface", J. Am. Chem. Soc.1999, 121, 8352.
  79. M. V. Mirkin"High Resolution Studies of Heterogeneous Processes with the Scanning Electrochemical Microscope", Mikrochimica Acta1999, 130, 127.
  80. Y. Shao, B. Liu and M. V. Mirkin"Studying Ionic Reactions by New Generation/Collection Technique", J. Am. Chem. Soc.1998, 120, 12700.
  81. Y. Shao and M. V. Mirkin"Probing Ion Transfer at the Liquid/Liquid Interface by Scanning Electrochemical Microscopy (SECM)",J. Phys. Chem. B1998, 102, 9915.(invited article; special issue)
  82. B. R. Horrocks and M. V. Mirkin"Cation Binding to DNA Studied by Ion Transfer Voltammetry at Micropipets", Anal. Chem.1998, 70, 4653.
  83. Y. Shao and M. V. Mirkin "Voltammetry at Micropipet Electrodes", Anal. Chem.1998, 70, 3155.
  84. B. R. Horrocks and M. V. Mirkin"Evidence for a Potential-Dependent Reversible Inactivation of Urease Adsorbed on a Gold Electrode",J. Chem. Soc. Faraday Trans.1998, 94, 1115.
  85. Y. Shao and M. V. Mirkin"Fast Kinetic Measurements with Nanometer-Sized Pipets. Transfer of Potassium Ion from Water into Dichloroethane Facilitated by Dibenzo-18-Crown-6", J. Am. Chem. Soc.1997, 119, 8103.
  86. M. Tsionsky, A. J. Bard and M. V. Mirkin"LongRange Electron Transfer Through a Lipid Monolayer at the Liquid/Liquid Interface", J. Am. Chem. Soc.1997, 119, 10785.
  87. F. Forouzan, A. J. Bard and M. V. Mirkin"Voltammetric and Scanning Electrochemical Microscopic Studies of the Adsorption Kinetics and Self-Assembly of n-Alkanethiol Monolayers on Gold", Isr. J. Chem.1997, 37, 155.(invited article; special issue)
  88. Y. Shao, M. V. Mirkin, G. Fish, S. Kokotov, D. Palanker and A. Lewis "Nanometer-Sized Electrochemical Sensors", Anal. Chem.1997, 69, 1627.
  89. Y. Shao, M. V. Mirkin and J. F. Rusling"Liquid/Liquid Interface as a Model System for Studying Electrochemical Catalysis in Microemulsions. Reduction of Trans-1,2-dibromocyclohexane with Vitamin B12", J. Phys. Chem. B1997, 101, 3202.
  90. Y. Shao and M. V. Mirkin"Scanning Electrochemical Microscopy (SECM) of Facilitated Ion Transfer at the Liquid/Liquid Interface", J. Electroanal. Chem.1997, 439, 137.(invited article; special issue)
  91. M. Tsionsky, A. J. Bard and M. V. Mirkin"Scanning Electrochemical Microscopy.  34.  Potential Dependence of the Electron-Transfer Rate and Film Formation at the Liquid/Liquid Interface",  J. Phys. Chem.1996, 100, 17881.
  92. M. V. Mirkin"Recent Advances in Scanning Electrochemical Microscopy (SECM)", Anal. Chem.1996, 68, 177A.
  93. C. Wei, A. J. Bard and M. V. Mirkin"Scanning Electrochemical Microscopy  31.  The Application of SECM to the Study of Charge Transfer Processes at the Liquid/Liquid Interface",  J. Phys. Chem.1995, 99, 16033.
  94. A. J. Bard, F.-R. F. Fan and  M. V. Mirkin"Scanning Electrochemical Microscopy ", in I. Rubinstein (Ed.), Physical Electrochemistry: Principles, Methods and Applications,  Dekker, N.Y., 1995, pp. 209 - 242.
  95. M. Arca, M. V. Mirkin and A. J. Bard"Polymer Films on Electrodes 26.  Study of Ion Transport and Electron Transfer at Polypyrrole Films by Scanning Electrochemical Microscopy", J. Phys. Chem.1995, 99, 5040.
  96. A. J. Bard, F.-R. F. Fan and  M. V. Mirkin"Scanning Electrochemical Microscopy ", in A. T. Hubbard (Ed.), Handbook of Surface Imaging and Visualization,  CRC, Boca Raton, 1995, pp. 667 -  680.
  97. B. R. Horrocks, M. V. Mirkin and A. J. Bard "Scanning Electrochemical Microscopy 25.  Investigation of the Kinetics of Heterogeneous Electron Transfer at Semiconductor (WSe2 and Si) Electrodes", J. Phys. Chem.1994, 98, 9106.
  98. A. J. Bard, F.-R. F. Fan and M. V. Mirkin"Scanning Electrochemical Microscopy", in A. J. Bard (Ed.), Electroanalytical Chemistry,Vol. 18, Marcel Dekker, N.Y.,1994, pp. 243 - 373.
  99. D. A. Treichel, M. V. Mirkin and A. J. Bard "Scanning Electrochemical Microscopy  27.  Application of a Simplified Treatment of an Irreversible Homogeneous Reaction Following Electron Transfer to the Oxidative Dimerization of 4-Nitrophenolate in Acetonitrile", J. Phys. Chem.1994, 98, 5751.
  100. F.-R. F. Fan, M. V. Mirkin and A. J. Bard"Polymer Films on Electrodes 25.  Effect of Polymer Resistance on the Electrochemistry of Poly(vinylferrocene): Scanning Electrochemical Microscopic, Chronoamperometric, and Cyclic Voltammetric Studies", J. Phys. Chem.1994, 98, 1475.
  101. M. V. Mirkin, M. Arca and A. J. Bard"Scanning Electrochemical Microscopy 22.  Examination of Thin Solid Films of AgBr: Ion Diffusion in the Film and Heterogeneous Kinetics at the Film/Solution Interface", J. Phys. Chem.1993, 97, 10790.
  102. M. V. Mirkin, T. C. Richards and A. J. Bard"Scanning Electrochemical Microscopy 20.  Steady-State Measurements of the Fast Heterogeneous Kinetics in the Ferrocene/Acetonitrile System", J. Phys. Chem.1993, 97, 7672.
  103. B. R. Horrocks, M. V. Mirkin, D. T. Pierce, A. J. Bard, G. Nagy and K. Toth"Scanning  Electrochemical  Microscopy 19.  Ion Selective Potentiostatic Microscopy",Anal. Chem.1993, 65, 1213.
  104. M. V. Mirkin, L. O. S. Bulhoes and A. J. Bard"Determination of the Kinetic Parameters for the Electroreduction of C60 by ScanningElectrochemical Microscopy and Fast Scan Voltammetry", J. Am. Chem. Soc.1993, 115, 201.
  105. M. V. Mirkin, F.- R. F. Fan and A. J. Bard"Direct Electrochemical Measurements Inside a 2000 Å- Thick Polymer Film by Scanning Electrochemical Microscopy", Science1992, 257, 364.
  106. M. V. Mirkin and A. J. Bard"A Simple Analysis of Quasi-reversible Steady-State Voltammograms", Anal. Chem.1992, 64, 2293.
  107. M. V. Mirkin and A. J. Bard"Scanning  Electrochemical  Microscopy 18. Thin Layer Cell Formation with a Mercury Pool Substrate", J. Electrochem. Soc.1992, 139, 3535.
  108. M. V. Mirkin, H. Yang and  A. J. Bard"Borohydride Oxidation at a Gold Electrode",  J. Electrochem. Soc.1992, 139, 2212.
  109. M. V. Mirkin, F.- R. F. Fan and A. J. Bard"Scanning Electrochemical Microscopy. 13. Evaluation of the Tip Shapes of nm-Size Microelectrodes", J. Electroanal. Chem.1992, 328, 47.
  110. M. V. Mirkin and A. J. Bard"Multidimensional Integral Equations: a New Approach to Solving Microelectrode Diffusion Problems",  J. Electroanal. Chem.1992, 323, 1.
  111. M. V. Mirkin and A. J. Bard"Multidimensional Integral Equations: a New Approach to Solving Microelectrode Diffusion Problems.  2. Application to Microband Electrodes, and Scanning Electrochemical Microscope",J. Electroanal. Chem.1992, 323, 29.
  112. A. J. Bard, M. V. Mirkin, P. R. Unwin and D. O. Wipf"Scanning Electrochemical Microscopy. 12. Theory and Experiment for Finite Heterogeneous Electron Transfer Kinetics and Arbitrary Substrate Size", J. Phys. Chem.1992, 96, 1861.
  113. G. Denuault, M. V. Mirkin and A. J. Bard"Direct Determination of Diffusion Coefficients by Chronoamperometry at Microdisk Electrode", J. Electroanal. Chem.1991, 308, 27.
  114. M. V. Mirkin"Computer Modeling 3-D Nucleation and Growth", Comput. Chem., 1991, 15, 169.
  115. M. V. Mirkin and A. J. Bard"A Voltammetric Method for the Determination of Borohydride Concentration in Alkaline Solutions", Anal. Chem.1991, 63, 532.
  116. M. V. Mirkin and A. P. Nilov"Modification of Huber Method for Solving Integral Equations on a Non-uniform Grid", Comput. Chem. 1991, 15, 55
  117. M. V. Mirkin and A. P. Nilov"Three-dimensional Nucleation and Growth Under Controlled Potential", J. Electroanal. Chem.1990, 283, 35.
  118. M. V. Mirkin, E. V. Nechepurenko and A. P. Nilov"Anode-Cathode Modification of the Linear Sweep Voltammetry", Editorial Board of "Soviet Electrochemistry", VINITI, 1990  (in Russian).
  119. M. V. Mirkin, A. P. Nilov and M. K. Nauryzbaev"General Method of Calculation of Polarization Curves for Different Analytical Techniques",  J. Electroanal. Chem.1990, 281, 41.
  120. M. V. Mirkin, A. P. Nilov and G. G. Kadisova"Antimony Electrodeposition on the Mercury Electrode", J. Electroanal. Chem.1989, 274, 319.
  121. M. V. Mirkin, A. P. Nilov and M. K. Nauryzbaev"Calculation of the Polarization curves for Electrochemical Studies. I. Polarography", Editorial Board of "Soviet Electrochemistry", VINITI, 1986  (in Russian).
  122. M. V. Mirkin, A. P. Nilov and M. K. Nauryzbaev"Calculation of the Polarization curves for Electrochemical Studies. II. Generalization of the Non-stationary Model. Cyclic Voltammetry", Editorial Board of "Soviet Electrochemistry", VINITI, 1986  (in Russian).
  123. M. V. Mirkin, A. P. Nilov and M. K. Nauryzbaev"Methods of Studying the Kinetics of Electrode Processes Based on Non-steady-state Model",Vestnik. Akad. Nauk KazSSR1985, 5, 61 (in Russian).

 

 

 

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